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In this dissertation I examine population history and structure in the Maya area during the Classic period (A.D. 250-900). Within the Maya area, archaeologists have identified regional variation in material culture between archaeological zones. These cultural differences may correspond to biological differences between Classic Maya populations. I test the hypothesis that Classic Maya population structure followed an isolation by distance model. I collected dental nonmetric and metric traits on 977 skeletons, from 18 Classic period sites, representing seven different archaeological zones. I corrected the data for intraobserver error. For the dental nonmetric data, I developed a Maya-specific trait dichotomization scheme and controlled for sex bias. I tested the dental metric data for normality and age affects. I imputed missing dental m...
Phosphofructokinase from Escherichia coli (EcPFK) is allosterically regulated by MgADP and phospho(enol)pyruvate (PEP). Both molecules compete for binding to the same allosteric site, however, MgADP activates and PEP inhibits the binding of fructose-6-phosphate (F6P) to the active site. The mode by which this enzyme can differentiate between the two ligands and cause the appropriate response is important for the understanding of the basis of allosteric regulation. We studied the interactions between an active site and an allosteric site (heterotropic interactions) within the protein, and found that each of the four unique heterotropic interactions is unique and the magnitudes of the coupling free energies for MgADP activation sum up to 100% that of wildtype EcPFK without homotropic cooperativity in F6P binding. We took on the kinetic a...
The Upper North Bosque River (UNBR) watershed is under a Total Maximum Daily Load (TMDL) mandate to reduce Phosphorus (P) due to excess nutrients in the watershed. To address these problems, Texas A&M University researchers have developed a turfgrass sod Best Management Practice (BMP) to remove excess nutrients from impaired watersheds. Turfgrass harvest of manure fertilized sod removes a thin layer of topsoil with most of the manure applied P. Plot and field scale research has demonstrated the effectiveness of turfgrass to remove manure phosphorus (P). In order to assess the impact of the turfgrass BMP on a watershed scale, the Soil and Water Assessment Tool (SWAT) was used to predict water quality in the UNBR watershed. The SWAT model was modified to incorporate turfgrass harvest routines to predict manure and soil P export through t...
Concentrated animal feeding operations (CAFOs) have caused water quality concerns in many rural watersheds, sometimes forcing the State of Texas to conduct Total Maximum Daily Load (TMDL) assessments of stream nutrients such as nitrogen (N) and phosphorus (P). One suggested Best Management Practice (BMP) is the export of phosphorus (P) through turfgrass sod produced with composted dairy manure from an impaired rural watershed to an urban watershed. The manure-grown sod releases P slowly and would not require additional P fertilizer for up to 20 years in the receiving watershed. This would eliminate P application to the sod and improve the water quality of urban streams. The Soil and Water Assessment Tool (SWAT) was used to model a typical suburban watershed that would receive the transplanted sod. The objective of the modeling was to d...
The work presents investigations into the development of a fuel-powered compact SMA actuator system. For the final SMA actuator, the K-alloy SMA strip (0.9 mm x 2.5 mm), actuated by a forced convection heat transfer mechanism, was embedded in a rectangular channel. In this channel, a rectangular piston, with a slot to accommodate the SMA strip, ran along the strip and was utilized to prevent mixing between the hot and the cold fluid in order to increase the energy density of the system. The fuel, such as propane, was utilized as main energy source in order to achieve high energy and power densities of the SMA actuator system. Numerical analysis was carried out to determine optimal channel geometry and to estimate maximum available force, strain and actuation frequency. Multi-channel combustor/heat exchanger and micro-tube heat exchange...
Changes with land cover and land use are closely integrated with water and other ecological processes at the land surface. Nowhere is that more apparent than in the Edwards Aquifer region of southcentral Texas. The Edwards Aquifer contributing and recharge zones cover approximately 18,000 square kilometers in parts of 15 counties in Texas and includes San Antonio and Austin, the nation's eighth and nineteenth largest cities, respectively. Population growth within the counties that intersect the Edwards Aquifer contributing and recharge zones has taken place over the last two decades, with the logical translation being an expanded infrastructure. This implies that a greater amount of impervious surface coverage and other land cover changes have occurred. This work quantified the changes in land cover within the Edwards Aquifer contribut...
This thesis contains an observational analysis of the genesis of Tropical Storm Allison (2001). Using a paradigm of tropical cyclone formation as the superposition of potential vorticity (PV) anomalies, the importance of different scales of PV merger to various aspects of Allison’s formation is discussed. While only the case of Allison is discussed in great detail, other studies have also documented PV superposition on various scales, and superposition could be important for most tropical cyclones. Preceding Allison’s genesis, PV superposition on the large scale destabilized the atmosphere and increased low-level cyclonic vorticity. This presented a more favorable environment for the formation of MCV-type PV anomalies and smaller, surface-based, meso-β-scale vortices. Although these vortices eventually merged to form a more concen...
During the period of June 29 through July 6, 2002, an extreme precipitation event occurred over Texas, resulting in catastrophic flooding. Operational forecasts performed poorly, neither predicting the copious amounts of rain nor its longevity. The Penn State University/NCAR Mesoscale Model version 5 (MM5) was used to conduct predictability experiments, which follow closely to the research conducted by Zhang et al. A control simulation initialized at 00Z 1 July is established over a 30-km grid. First, practical predictability experiments are performed by exploring the impacts due to different lead-times, resolution dependence, and different physics parameterizations. Second, intrinsic predictability is investigated by inducing a random temperature perturbation in the initial conditions, followed by numerous simulations with various per...
Community Climate Model 3 (CCM3) is run on an idealized all land zonally symmetric planet (Terra Blanda) with no seasonality, no snow and fixed soil moisture to obtain a stationary time series effectively much longer than conventional runs with geography and seasons. The surface temperature field generated is studied to analyze the spatial and temporal spectra, estimate the length scale and time scale of the model, and test the linearity of response to periodic and steady heat source forcings. The length scale of the model is found to be in the range of 1000-2000 km and the time scale is estimated to be 24 days for the global average surface temperature field. The response of the global average temperature is found to be fairly linear to periodic and the steady heat source forcings. The results obtained are compared with the results of...
Linoleum has been around for over a hundred years. With its invention by Frederick Walton in the 1860’s a new means of durable floor covering was introduced to the world. This new invention was promoted as durable, hygienic, and easy to maintain. In agreement with the Lake Champlain Maritime Museum, a study was commissioned to seek the best means to conserve linoleum from a canal boat excavated in the summer of 2002 in Lake Champlain. The Sloop Island Canal Boat is part of an excavation project that is studying the ways of life on the lake. Conserving waterlogged linoleum is a new area of study in conservation, and there is very little information dealing with the topic. This study will provide a baseline for the conservation of linoleum.
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